df.sort_values(by=col1,asending=True)

72

df.sort_values(by='col1',asending=True) -

>>> df.sort_values(by='col1', ascending=False)
  col1  col2  col3 col4
4    D     7     2    e
5    C     4     3    F
2    B     9     9    c
0    A     2     0    a
1    A     1     1    B
3  NaN     8     4    D

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