dictionary from two columns pandas

pd.Series(df.A.values,index=df.B).to_dict()

In [6]: df = pd.DataFrame(randint(0,10,10000).reshape(5000,2),columns=list('AB'))

In [7]: %timeit dict(zip(df.A,df.B))
1000 loops, best of 3: 1.27 ms per loop

In [8]: %timeit pd.Series(df.A.values,index=df.B).to_dict()
1000 loops, best of 3: 987 us per loop

In [9]: pd.Series(df.Letter.values,index=df.Position).to_dict()
Out[9]: {1: 'a', 2: 'b', 3: 'c', 4: 'd', 5: 'e'}

In [2]: df = pd.DataFrame({'a':[1,2,3], 'b':[{'c':1}, {'d':3}, {'c':5, 'd':6}]})

In [3]: df
Out[3]:
   a                   b
0  1           {u'c': 1}
1  2           {u'd': 3}
2  3  {u'c': 5, u'd': 6}

In [4]: df['b'].apply(pd.Series)
Out[4]:
     c    d
0  1.0  NaN
1  NaN  3.0
2  5.0  6.0

sales = [{'account': 'Jones LLC', 'Jan': 150, 'Feb': 200, 'Mar': 140},
         {'account': 'Alpha Co',  'Jan': 200, 'Feb': 210, 'Mar': 215},
         {'account': 'Blue Inc',  'Jan': 50,  'Feb': 90,  'Mar': 95 }]
df = pd.DataFrame(sales)